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ML00002 - Jan.2018

Preferential Dissolution and Cracks in SDSS

Visual aspect from the external side of the 14"ND flange butt welded to a pipe, presenting a through wall crack about 5mm to 10mm from the butt welding.

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925
Visual aspect from the external side of the 14" butt welded to a , presenting a through wall about 5mm to 10mm from the butt .
M

Material

Super Duplex Stainless Steel
  • UNS S32750
  • ASTM A 182 grade F53
Ds

Description

The operational temperature of the is 90°C and the was replaced after a very short time in operational due to a in the base material. The flange rusted since the spool was assembled and the is associated to preferential dissolution and associated to the with the presence of .

C

Chemistry (% in weight)

Product Analysis, without N

0.042C; 0.37Si; 0.84Mn; 0.005P; 0.002S; 25.12Cr; 7.20Ni; 3.52Mo; 0.21Cu.

Associated Images
Visual aspect from the external side of the 14"ND flange butt welded to a pipe, presenting a through wall crack about 5mm to 10mm from the butt welding.
925
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Aspect Before AnalysisDf - Through Wall Cracking
External surface aspect of the flange showing preferential dissolution, responsible for nucleation of the through wall cracking.
245
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Surface Aspect by SEMDf - Preferential Dissolution
Detail of the region at the flange external surface where the material is suffering the preferential corrosion.
177
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Surface Aspect by SEMDf - Preferential Dissolution
Macrography of a longitudinal section of the flange to pipe weld, cracked in the flange. Pipe thickness, measured, is 5 mm. Flange thickness at the welded region is 7.5 mm. The macro was etched using NaOH solution, electrolytic.
181
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MacroDf - Longitudinal Section
Macrography transverse to the circunferential weld, longitudinal to the piping, presenting the location, a little far from the welded joint margin, where the through wall cracking is positioned.
160
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Through Wall Cracking
Longitudinal section micrography at the cracked position, close to the external surface of the flange, showing cracks transverse to the thickness, associated to the microstructure.
147
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Cracks Transverse to the Surface
Longitudinal section micrography at the cracked position, close to the internal surface of the flange (exposed to the corrosive fluid), showing preferential dissolution associated to the microstructure.
133
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Preferential Dissolution
Micrographic detail of the through wall cracking in the middle of the thickness, showing that the cracking is associated to ferrite network in the (super)duplex microstructure.
128
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Micrography by SEMDf - Crack
Micrographic detail of the cracking, associated to the ferrite network, that presents both corrosion (preferential dissolution) and fracture (clevage) aspects.
128
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Electrolytic Etch Micrography by SEMDf - Crack
After a longitudinal section of the flange to pipe weld, the through wall cracking opened in two parts and the fracture surface was analyzed. The flange side fracture surface is presented in this figure.
126
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Aspect Before AnalysisDf - Fracture
The fracture surface, although presenting a large amount of corrosion products, shows also evidences of a brittle behavior with regions of cleavage micromechanism.
116
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Fractography by SEMDf - Cleavage Facets
Micrography of the flange in the longitudinal section. The flange microstructure is ferritic austenitic, presenting a coarse structure.
102
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Coarse Structure
Micrographic detail of the flange microstructure in the longitudinal section. The flange is ferritic austenitic, presenting 70% of austenite. In the ferrite network there are evidences of precipitation/formation of detrimental phases.
113
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Duplex structure
Micrographic detail of the flange microstructure in the longitudinal section. The flange is ferritic austenitic, presenting 70% of austenite. In the ferrite network there are evidences of precipitation/formation of detrimental phases.
100
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - NaOH Electrolytic Etched MicroDf - Duplex structure
Micrographic detail of the ferrite network with evidences of precipitation/formation of detrimental phases. NaOH solution was adopted for the electrolytic etching.
86
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Electrolytic Etch Micrography by SEMDf - Delta ferrite
Fracture surface of the broken Charpy V testpiece, tested at ambient temperature and presenting only 10J average energy. The brittle fracture presented cleavage facets associated to the detrimental phases in the ferrite network.
84
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Fractography by SEMDf - Cleavage Facets
Detail of the fracture surface of the broken Charpy V testpiece, tested at ambient temperature and presenting only 10J average energy. The brittle fracture presented cleavage facets associated to the detrimental phases in the ferrite network.
89
VIEW
ML00002 / Jan.2018
Preferential Dissolution and Cracks in SDSS
M - Super Duplex Stainless SteelP - Fabrication WeldAp - PipingCd - Preferential Dissolution
Cm - Fractography by SEMDf - Cleavage Facets