Back to Austenitic / Martensitic
ML00121 - Feb.2018

Pitting Corrosion in a Subsea System

Nitronic 60 cylinder. Scanning electron microscopy image of a corroded region at the external surface of the cylinder, that is austenitic. The image shows the localized corroded regions in form of pits.

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cylinder. image of a corroded region at the of the cylinder, that is austenitic. The image shows the localized corroded regions in form of pits.
M

Material

Austenitic / Martensitic
  • UNS S21800
  • ASTM A 479 grade S21800
  • UNS S17400
  • ASTM A 564 grade S17400 H1150D
Ds

Description

The control system was in operation at a water depth about 1500 meters and failed after a few months due to a through wall for the tubular part. The metallurgical analysis showed that both parts, cylinder and 17-4 PH , corroded in seawater because the control system was not properly connected to the system.

C

Chemistry (% in weight)

Cylinder

0.07C; 3.24Si; 7.55Mn; 0.025P; 0.006S; 16.77Cr; 8.57Ni; 0.08Mo; 0.16Nb; 0.35Cu.

Rod

0.06C; 0.36Si; 0.70Mn; 0.030P; 0.006S; 15.35Cr; 4.31Ni; 0.07Mo; 0.36Nb; 3.01Cu.

Associated Images
Nitronic 60 cylinder. Scanning electron microscopy image of a corroded region at the external surface of the cylinder, that is austenitic. The image shows the localized corroded regions in form of pits.
1228
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface Aspect by SEMDf - Localized Corrosion
Aspect of the Nitronic 60 cylinder, OD 36.4mm, presenting pits at the external surface.
219
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Aspect Before AnalysisDf - External Surface
Nitronic 60 cylinder. Detailed aspect of the pitting in a low magnification microscope.
197
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface AspectDf - Pitting
Nitronic 60 cylinder. Micrography of the longitudinal section in the center of the thickness, presenting a fully austenitic microstructure, equiaxial grains, and evidences of the manufacturing process by hot forming.
179
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Austenite
Nitronic 60 cylinder. Micrography of the longitudinal section in the center of the thickness, presenting a fully austenitic microstructure, with some aligned non metallic inclusions.
157
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Austenite
Nitronic 60 cylinder. Micrographic detail of the longitudinal section in the center of the thickness, presenting a fully austenitic microstructure, equiaxial grains, typical of a solution annealed condition.
136
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Austenite
Nitronic 60 cylinder. Micrography of the longitudinal section close to the surface, presenting a fully austenitic microstructure, with a shadow close to the external surface that is associated to a small layer of strain hardened structure (deformation twins).
133
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Strain Hardened
Nitronic 60 cylinder. Micrography of the longitudinal section close to the surface, presenting a fully austenitic microstructure, with a 0.15mm layer of strain hardened structure (deformation twins).
120
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Strain Hardened
Nitronic 60 cylinder. Micrographic detail of the longitudinal section close to the surface, presenting a fully austenitic microstructure, with a layer of strain hardened structure (deformation twins).
113
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Micrography by OM using A262 Method ADf - Strain Hardened
Nitronic 60 cylinder. Scanning electron microscopy image of a corroded region at the external surface of the cylinder, that is austenitic. The image shows the structure revealed by dissolution of the material (inside the pits) evidencing the strain hardened layer that is presented at the cylinder surface due to the manufacturing process.
106
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface Aspect by SEMDf - Localized Corrosion
Nitronic 60 cylinder. Scanning electron microscopy image detail of a corroded region inside a pitting showing the etched structure (strain hardened austenitic structure).
103
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface Aspect by SEMDf - Localized Corrosion
Nitronic 60 cylinder. Scanning electron microscopy image of a corroded region in a pit, at the external surface of the cylinder. The corrosion (dissolution) revealed the strain hardened layer at the surface.
96
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface Aspect by SEMDf - Localized Corrosion
Aspect of the 17-4 PH rod, OD 10.6 mm, presenting deep pits at the external surface.
125
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Aspect Before AnalysisDf - External Surface
17-4 PH rod. Detailed aspect of the pitting in a low magnification microscope.
115
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface AspectDf - Pitting
17-4 PH rod, tubular, OD 10.6mm, wall thickness about 3.5 mm. Macrography of the rod in a transverse section showing the pitting in a position where it is almost through wall.
86
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Kalling Etched MacroDf - Pitting
17-4 PH rod. Micrography of the longitudinal section in the center of the thickness, presenting an aged martensitic structure. The darker lines are bands of (sligthly) segregated regions. This material presents properties that correspond to the H1150 grade.
73
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Kalling Etched Micrography by OMDf - Martensite
17-4 PH rod. Micrography of the longitudinal section in the center of the thickness, presenting an aged martensitic structure. The darker lines are bands of (sligthly) segregated regions. This material presents properties that correspond to the H1150 grade.
66
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Kalling Etched Micrography by OMDf - Martensite
17-4 PH rod. Micrographic detail of the aged martensitic structure. At this magnification level the previous austenite grain boundaries are evidenced. It is also possible to see that the bands of (sligthly) segregated regions are all martensitic.
64
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Kalling Etched Micrography by OMDf - Martensite
17-4 PH rod. Micrography of the longitudinal section close to the surface, presenting the roughness (the waves at the surface) and a region where a pitting was still in the beginning, not related to any specific microstructure.
70
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Kalling Etched Micrography by OMDf - Pitting
17-4 PH rod. Surface aspect by scanning electron microscopy showing a region where the passivation layer was destroyed and a pitting was in the begining.
86
VIEW
ML00121 / Feb.2018
Pitting Corrosion in a Subsea System
M - Austenitic / MartensiticP - Rod & CylinderAp - SubseaCd - Pitting Corrosion
Cm - Surface Aspect by SEMDf - Pitting